Published Sep 10, 2009
Kamdyn
55 Posts
Hi everyone, I am in desperate need of some explaining!!! We have our first chem lab today and I have a pre-lab assignment I'm just NOT getting!!! (I swear he hasn't gone over any of this stuff in class yet)
So the first thing we had to do was calculate the volume of ice and water, which I did.
Ice: (mass) 1.000/(density) 0.9168= (volume)1.090750436
Water (mass) 1.000/(density) 0.9999= (volume)1.00010001
The next question is this: A sealed glass container with a capacity of exactly 100mL contains 96.0 mL of liquid water a 0 degrees C. If the water freezes, will the container rupture?
I'm really confused because doesn't water freeze at 0 degrees C? So how can water be at a liquid state at this temp? I'm not sure what the answer is or how to answer it!! Ughhh
I also do not know how to answer the following question:
A perfect cube of aluminum metal was found to weigh 20.00 g. The density of aluminum is 2.70 g mL -1. What are the dimensions of the cube?
I would ask my teacher but we're expected to hand this in when we get to lab today... Can someone please show me how to do these problems?!?!
Thanks SOO much for any and all help!!
TRR8021
157 Posts
Well, the answer to the 1st question is that yes, the container will rupture. Water has a unique property in that it expands as it freezes and the molecules spread out instead of packing together (due to hydrogen bonding.) That's why ice is less dense than water and floats in water.
As for the second part, a mL is the same as cc (or cubic centimeter) so the dimensions of the cube would be the mass divided by the density: (20.00 g)/(2.70 g/mL)= 7.41 mL or 7.41 cc, rounded to 3 sig figs.
I hope that helps. Good luck in chem!! :)
Well, the answer to the 1st question is that yes, the container will rupture. Water has a unique property in that it expands as it freezes and the molecules spread out instead of packing together (due to hydrogen bonding.) That's why ice is less dense than water and floats in water.As for the second part, a mL is the same as cc (or cubic centimeter) so the dimensions of the cube would be the mass divided by the density: (20.00 g)/(2.70 g/mL)= 7.41 mL or 7.41 cc, rounded to 3 sig figs.I hope that helps. Good luck in chem!! :)
Thank you thank you thank you!!!! I have been looking through my book trying to find these formulas!!! And thanks for the good luck! I'm going to need it! Haha
Guest 360983
357 Posts
I hope I'm not too late to help you!!
I imagine that your professor is looking for some calculations.
First, significant figures for your calcuations!! My old major required lots of chemistry, so I took lots of chemistry classes, and always had to pay attention to significant figures. I can link a site if you need an explanation.
Using significant figures, your ice density will be 1.091 g/mL. Your water density will be 1.000 g/mL. I'm assuming g & mL here, but substitute whatever measurement unit you used.
Your ice density is weird. I'm not trying to blame you (you did the math right), but ice ought to be less dense than water; this is what makes it float in water. The only reason I'm mentioning this is because it will mess with your answer for #1.
1. I think you're overthinking this problem. I do that a lot :)
Basically, you need to find the volume of the water when it turns to ice. You know the density of water and ice, and the volume of water. The mass of the water will be the same whether it's liquid or solid. Use the density formula to get the mass of water.
D=M/V
1.000=M/96.0
M=(1.000*96.0)
M=96.0 g
Now you know the mass of the ice and the density of it, so you can determine the volume it will occupy.
1.091=96.0/V
V=96.0/1.091
V=87.99 mL
This volume is less than the 100 mL container, so it will not shatter. See how the weird density changes the answer?
2. TRR was right in that the volume of the cube is 7.41 cc, but the question is asking for the dimensions of the cube. Volume is length x width x height; in a cube, they're all the same so (length cubed)=Volume; the cube root of 7.41, adjusted for sig figs, is 1.95 cc.
Good luck, hope I got to you in time, and I'll be happy to help with anything else (chemistry wise, anyways )
Hmm, I don't know about the volume thing. The water loses volume when it freezes? Kamdyn, you'll have to let us know what your teacher says on that one lol. I think the trick of the question is that we'd logically think that 96.0
And yes, take the cube root to find the dimensions! Sorry!! So it would be 1.95 cc x 1.95 cc x 1.95 cc (length x width x height.)
I knew the answer wasn't right, but I just figured it out.
(It would probably help if I read everything more closely)
I got your density for ice wrong--you have .9168 g/mL.
So, editing in correct numbers, you have a mass of 95.90 g, leading to a volume of 104.6 mL. The glass will shatter.
So sorry to mess you up!!