Although it would be nice to volunteer at a local hospital, I highly recommend that you work part-time as a CNA, tech, secretary, admin assistant, etc. within a hospital. This approach will help you in the long run when you are done with nursing school and get licensed because nowadays internal employees get first dibs on available nursing positions within any given hospital. This specific environment will also give you a better advantage to start networking while you're in the program and yes, this will give you the opportunity to work with nurses. Working as a CNA would be my top choice because the very first portion/months of nursing school covers the basics/fundamentals in which your experience as a CNA may come in handy. If attending a CNA program doesn't please you, try looking into secretary positions in postop, ICU, PACU, tele, or surgical units. You won't need clinical experience or certifications for that. Bottom line is get a job in a hospital and while you are job hunting, volunteering a few hours a week won't hurt. Good luck!