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need help,,,micro question



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Jun 02, 2009 06:46 AM

need help,,,micro question

by BethT

BACKGROUND INFORMATION
Kesterson National Wildlife Refuge, California. In the San Joaquin Valley, irrigation water wasn't draining properly, and crops were dying in the water-logged soil. In 1981, a drainage system was built that would channel irrigation runoff into shallow ponds called Kesterson Reservoir. In addition to receiving field runoff, the new reservoir was to be a waterfowl habitat. In 1983, an unusually large number of dead birds was found, indicating that something was wrong with the water.
Selenium from the soil (in the form of selenate, SeO42-) was dissolving in the irrigation water and being carried to Kesterson Reservoir, where it stayed. The concentration of selenium in Kesterson rose to 29 times higher than that which was considered safe.
For now, to prevent the killing of more birds, Kesterson Reservoir is being filled with soil. But the selenium remains.
A number of bacteria, including Bacillus, Acinetobacter, and Pseudomonas, can convert selenate (SeO42-) to nontoxic elemental selenium. The bacteria do this for their own survival-to prevent the accumulation of toxic levels in their cells.

I have to show the chemical reaction for this, I have no idea what I am doing. Can someone point me in the right direction?


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from victa88
Old Jun 02, 2009, 06:18 PM

Default Re: need help,,,micro question
Thats a tough question for only being a nursing Micro. But looking through some of my upper division micro books I came up with this H2Se03 converts to CH3Se03H by the way of methylation. Then CH3Se03H converts to CH3Se02- by Ionization and reduction. Then CH3Se02- converts to (CH3)2Se02 by methylation. then that converts to (CH3)2 Se by reduction. All the numbers next to the letters r subscripts sorry! I hope this helps though. If it is wrong im sorry let me know and ill try to figure it out again. Goodluck

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